Kim Sang Hoon, KumarO R, Algarni H, Kumar G
J Nanosci Nanotechnol. 2015 Sep;15(9):6807-12. doi: 10.1166/jnn.2015.11597.
Well-crystalline ZnO nanoparticles were prepared through simple, facile and rapid solution combustion process and utilized as photoanode material for the fabrication of dye-sensitized solar cell. The detailed characterizations of the ZnO nanoparticles revealed that the crystalline product with wurtzite hexagonal phase was grown in high-density. The chemical composition analyzed through FTIR and EDS confirmed the purity of the ZnO nanoparticles. UV-vis and Raman spectral studies were applied for studying the optical and vibrational properties of as prepared ZnO nanoparticles, respectively. The fabricated dye-sensitized solar cell exhibited overall photo-to-electricity conversion efficiency (η) of 0.94%, open-circuit current (V(oc)) of 0.531 V, short circuit current (J(sc)) of 4.11 mA/cm2 and fill factor (FF) of 0.43.
通过简单、便捷且快速的溶液燃烧法制备了结晶良好的ZnO纳米颗粒,并将其用作制备染料敏化太阳能电池的光阳极材料。对ZnO纳米颗粒的详细表征表明,具有纤锌矿六方相的结晶产物以高密度生长。通过傅里叶变换红外光谱(FTIR)和能谱分析(EDS)分析的化学成分证实了ZnO纳米颗粒的纯度。分别应用紫外可见光谱和拉曼光谱研究了所制备的ZnO纳米颗粒的光学和振动性质。所制备的染料敏化太阳能电池的总体光电转换效率(η)为0.94%,开路电压(V(oc))为0.531 V,短路电流(J(sc))为4.11 mA/cm2,填充因子(FF)为0.43。