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Au@Ag@SiO2核壳纳米颗粒的Ag壳层厚度对染料敏化太阳能电池光电性能的影响

The Ag shell thickness effect of Au@Ag@SiO2 core-shell nanoparticles on the optoelectronic performance of dye sensitized solar cells.

作者信息

Wang Yang, Zhai Jin, Song Yanlin, He Ling

机构信息

Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, Beijing Key Laboratory of Bio-inspired Energy Materials and Devices, School of Chemistry and Environment, Beihang University, Beijing 100191, PR China.

School of science, Xi`an Jiaotong University, 710049, Xi`an, PR China.

出版信息

Chem Commun (Camb). 2016 Feb 7;52(11):2390-3. doi: 10.1039/c5cc08827e.

Abstract

To tailor the Au@Ag@SiO2 LSPR effect by varying the Ag shell thickness, the Au@Ag@SiO2 core-ultra-thin shell nanoparticles are fabricated and introduced into DSSC for improving light harvesting and decreasing the recombination of photo-carriers. The Au@Ag@SiO2 electrode exhibits a photo-conversion efficiency of 23.42% (486.7 nm, 10 mW cm(-2)).

摘要

为了通过改变银壳层厚度来调整金@银@二氧化硅的局域表面等离子体共振效应,制备了金@银@二氧化硅核-超薄壳层纳米颗粒,并将其引入到染料敏化太阳能电池中,以改善光捕获并减少光生载流子的复合。金@银@二氧化硅电极在486.7 nm、10 mW cm(-2)条件下表现出23.42%的光转换效率。

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