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外部场中石墨烯纳米带的电学和光学性质。

Electronic and optical properties of graphene nanoribbons in external fields.

作者信息

Chung Hsien-Ching, Chang Cheng-Peng, Lin Chiun-Yan, Lin Ming-Fa

机构信息

Department of Physics, National Cheng Kung University, Tainan 70101, Taiwan.

Center for General Education, Tainan University of Technology, Tainan 701, Taiwan.

出版信息

Phys Chem Chem Phys. 2016 Mar 21;18(11):7573-616. doi: 10.1039/c5cp06533j.

Abstract

A review work is done for the electronic and optical properties of graphene nanoribbons in magnetic, electric, composite, and modulated fields. Effects due to the lateral confinement, curvature, stacking, non-uniform subsystems and hybrid structures are taken into account. The special electronic properties, induced by complex competitions between external fields and geometric structures, include many one-dimensional parabolic subbands, standing waves, peculiar edge-localized states, width- and field-dependent energy gaps, magnetic-quantized quasi-Landau levels, curvature-induced oscillating Landau subbands, crossings and anti-crossings of quasi-Landau levels, coexistence and combination of energy spectra in layered structures, and various peak structures in the density of states. There exist diverse absorption spectra and different selection rules, covering edge-dependent selection rules, magneto-optical selection rule, splitting of the Landau absorption peaks, intragroup and intergroup Landau transitions, as well as coexistence of monolayer-like and bilayer-like Landau absorption spectra. Detailed comparisons are made between the theoretical calculations and experimental measurements. The predicted results, the parabolic subbands, edge-localized states, gap opening and modulation, and spatial distribution of Landau subbands, have been identified by various experimental measurements.

摘要

对石墨烯纳米带在磁场、电场、复合场和调制场中的电子和光学性质进行了综述。考虑了横向限制、曲率、堆叠、非均匀子系统和混合结构等因素的影响。由外部场与几何结构之间复杂竞争所诱导的特殊电子性质包括许多一维抛物子带、驻波、特殊的边缘局域态、宽度和场依赖的能隙、磁量子化准朗道能级、曲率诱导的振荡朗道子带、准朗道能级的交叉和反交叉、层状结构中能谱的共存和组合以及态密度中的各种峰结构。存在多种吸收光谱和不同的选择规则,包括边缘依赖选择规则、磁光选择规则、朗道吸收峰的分裂、组内和组间朗道跃迁,以及单层状和双层状朗道吸收光谱的共存。对理论计算和实验测量进行了详细比较。各种实验测量已经证实了预测结果,即抛物子带、边缘局域态、能隙打开和调制以及朗道子带的空间分布。

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