Departamento de Química Inorgánica and Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid (UAM), 28049 Madrid, Spain.
Chem Commun (Camb). 2016 Mar 18;52(22):4113-27. doi: 10.1039/c5cc10283a.
2D-polymers are still dominated by graphene and closely related materials such as boron nitride, transition metal sulphides and oxides. However, the rational combination of molecules with suitable design is already showing the high potential of chemistry in this new research field. The aim of this feature article is to illustrate, and provide some perspectives, the current state-of-the-art in the field of synthetic 2D-polymers showing different alternatives to prepare this novel type of polymers based on the rational use of chemistry. This review comprises a brief revision of the essential concepts, the strategies of preparation following the two general approaches, bottom-up and top-down, and a revision of the promising seminal properties showed by some of these nanomaterials.
二维聚合物仍然以石墨烯和与之密切相关的材料为主,如氮化硼、过渡金属硫化物和氧化物。然而,分子与合适设计的合理组合已经在这个新的研究领域展示出了化学的巨大潜力。本文的目的是举例说明并提供一些观点,展示化学在合成二维聚合物领域的最新进展,展示了基于合理利用化学的新型聚合物的不同制备方法。这篇综述包括对基本概念的简要回顾、遵循自上而下和自下而上两种一般方法的制备策略,以及对其中一些纳米材料所表现出的有前途的基本特性的回顾。