Programa de Celulosa y Papel, Instituto de Materiales de Misiones, IMAM (UNaM-CONICET), Félix de Azara 1552, Posadas, Misiones, Argentina; Consejo Nacional de Investigación Científica (CONICET), Av. Rivadavia 1917, CABA, Argentina.
Programa de Celulosa y Papel, Instituto de Materiales de Misiones, IMAM (UNaM-CONICET), Félix de Azara 1552, Posadas, Misiones, Argentina.
Carbohydr Polym. 2016 Mar 30;139:99-105. doi: 10.1016/j.carbpol.2015.12.004. Epub 2015 Dec 10.
Nanofibrillated cellulose has been obtained from the cellulosic fraction of eucalyptus sawdust. The fractionation process involved the partial removal of hemicelluloses and lignin. CNF was obtained using TEMPO oxidation with NaOCl in basic medium followed by mechanical homogenization. The obtained CNF was subsequently used as a dry strength agent on unbleached unrefined eucalyptus pulp. The addition of 3, 6 and 9 wt.% of CNF increased lineally the tensile index of handsheets to about 55 N mg(-1) at 35°SR, compatible with papermachine runnability. The other mechanical properties also increased substantially, and porosity decreased moderately. The estimated specific surface and average diameter of these CNF were 60 m(2)g(-1), and of 41.0 nm, respectively. The addition of 9 wt.% of CNF produced an increase in mechanical strength, equivalent to that produced by PFI refining at 1600 revolutions.
从桉树锯末的纤维素部分获得了纳米原纤纤维素。分馏过程涉及半纤维素和木质素的部分去除。通过 TEMPO 氧化在碱性介质中用 NaClO 获得 CNF,然后进行机械均化。所得 CNF 随后用作未漂未精制桉树纸浆的干强度剂。添加 3wt.%、6wt.%和 9wt.%的 CNF 使手抄片的抗张指数线性增加到约 35°SR 时的 55 N mg(-1),与纸机运行性能兼容。其他机械性能也有显著提高,孔隙度适度降低。这些 CNF 的比表面积和平均直径估计分别为 60 m(2)g(-1)和 41.0nm。添加 9wt.%的 CNF 可提高机械强度,相当于在 1600 转时进行 PFI 精制的效果。