Central European Institute of Technology, Masaryk University, Kotlářská 2, 61137 Brno, Czech Republic.
Max Planck Institute for Solid State Research, Heisenbergstrasse 1, D-70569 Stuttgart, Germany.
Phys Rev Lett. 2016 Jan 8;116(1):017203. doi: 10.1103/PhysRevLett.116.017203.
We study the effects of electron doping in Mott insulators containing d(4) ions such as Ru(4+), Os(4+), Rh(5+), and Ir(5+) with J=0 singlet ground state. Depending on the strength of the spin-orbit coupling, the undoped systems are either nonmagnetic or host an unusual, excitonic magnetism arising from a condensation of the excited J=1 triplet states of t(2g)(4). We find that the interaction between J excitons and doped carriers strongly supports ferromagnetism, converting both the nonmagnetic and antiferromagnetic phases of the parent insulator into a ferromagnetic metal, and further to a nonmagnetic metal. Close to the ferromagnetic phase, the low-energy spin response is dominated by intense paramagnon excitations that may act as mediators of a triplet pairing.
我们研究了具有 J=0 单线基态的 d(4)离子(如 Ru(4+)、Os(4+)、Rh(5+)和 Ir(5+))的莫特绝缘体中电子掺杂的影响。根据自旋轨道耦合的强度,未掺杂的系统要么是非磁性的,要么存在一种不寻常的激子磁性,这种磁性源于 t(2g)(4)的激发 J=1 三重态的凝聚。我们发现 J 激子与掺杂载流子之间的相互作用强烈支持铁磁性,将母体绝缘体的非磁性和反铁磁相都转化为铁磁金属,进一步转化为非磁金属。在铁磁相附近,低能自旋响应主要由强烈的 paramagnon 激发主导,这些激发可能作为三重态配对的介导者。