Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstrasse 30, 48149, Münster, Germany.
Organisch-chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149, Münster, Germany.
Angew Chem Int Ed Engl. 2016 Feb 24;55(9):3212-5. doi: 10.1002/anie.201511048. Epub 2016 Feb 2.
Hydroalumination of an alkynylphosphine gave an unprecedented P-H functionalized frustrated Lewis pair (FLP). The reactive P-H group does not influence the typical FLP properties, but the activation of substrates follows a new reaction pattern involving hydrogen transfer to yield unusual compounds with phosphaurea, iminophosphine, or phosphanyltriazene structural motifs.
炔基膦的水合铝化反应得到了一个前所未有的 P-H 官能化的受阻路易斯对（FLP）。反应性的 P-H 基团并不影响典型的 FLP 性质，但底物的活化遵循一种新的反应模式，涉及氢转移，生成具有磷脲、亚胺基膦或磷杂三嗪结构的不寻常化合物。
