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用于二氧化碳捕获应用的金属有机框架和多孔聚合物网络的评估

Evaluation of Metal-Organic Frameworks and Porous Polymer Networks for CO2 -Capture Applications.

作者信息

Verdegaal Wolfgang M, Wang Kecheng, Sculley Julian P, Wriedt Mario, Zhou Hong-Cai

机构信息

Department of Chemistry, Texas A&M University, College Station, TX, 77843, USA.

Department Chemistry & Biomolecular Science, Clarkson University, Potsdam, NY, 13699-5810, USA.

出版信息

ChemSusChem. 2016 Mar 21;9(6):636-43. doi: 10.1002/cssc.201501464. Epub 2016 Feb 3.

Abstract

This manuscript presents experimental data for 20 adsorption materials (metal-organic frameworks, porous polymer networks, and Zeolite-5A), including CO2 and N2 isotherms and heat capacities. With input from only experimental data, working capacities per energy for each material were calculated. Furthermore, by running seven different carbon-capture scenarios in which the initial flue-gas composition and process temperature was systematically changed, we present a range of performances for each material and quantify how sensitive each is to these varying parameters. The presented calculations provide researchers with a tool to investigate promising carbon-capture materials more easily and completely.

摘要

本手稿展示了20种吸附材料(金属有机框架、多孔聚合物网络和5A分子筛)的实验数据,包括二氧化碳和氮气等温线以及热容。仅根据实验数据输入,计算了每种材料的单位能量工作容量。此外,通过运行七种不同的碳捕获方案,其中系统地改变了初始烟气组成和工艺温度,我们展示了每种材料的一系列性能,并量化了每种材料对这些变化参数的敏感程度。所呈现的计算为研究人员提供了一种工具,以便更轻松、更全面地研究有前景的碳捕获材料。

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