Verdegaal Wolfgang M, Wang Kecheng, Sculley Julian P, Wriedt Mario, Zhou Hong-Cai
Department of Chemistry, Texas A&M University, College Station, TX, 77843, USA.
Department Chemistry & Biomolecular Science, Clarkson University, Potsdam, NY, 13699-5810, USA.
ChemSusChem. 2016 Mar 21;9(6):636-43. doi: 10.1002/cssc.201501464. Epub 2016 Feb 3.
This manuscript presents experimental data for 20 adsorption materials (metal-organic frameworks, porous polymer networks, and Zeolite-5A), including CO2 and N2 isotherms and heat capacities. With input from only experimental data, working capacities per energy for each material were calculated. Furthermore, by running seven different carbon-capture scenarios in which the initial flue-gas composition and process temperature was systematically changed, we present a range of performances for each material and quantify how sensitive each is to these varying parameters. The presented calculations provide researchers with a tool to investigate promising carbon-capture materials more easily and completely.
本手稿展示了20种吸附材料（金属有机框架、多孔聚合物网络和5A分子筛）的实验数据，包括二氧化碳和氮气等温线以及热容。仅根据实验数据输入，计算了每种材料的单位能量工作容量。此外，通过运行七种不同的碳捕获方案，其中系统地改变了初始烟气组成和工艺温度，我们展示了每种材料的一系列性能，并量化了每种材料对这些变化参数的敏感程度。所呈现的计算为研究人员提供了一种工具，以便更轻松、更全面地研究有前景的碳捕获材料。
