基于多氧钒酸盐的有机-无机杂化物：从{V5O9Cl}簇到纳米尺寸的八面体笼
Polyoxovanadate-based organic-inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages.
作者信息
Zhang Yu-Teng, Wang Xin-Long, Zhou En-Long, Wu Xue-Song, Song Bai-Qiao, Shao Kui-Zhan, Su Zhong-Min
机构信息
Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China.
出版信息
Dalton Trans. 2016 Mar 7;45(9):3698-701. doi: 10.1039/c5dt04764a.
Three polyoxovanadate-based metal-organic polyhedra (denoted as VMOP-1, -2, and -3), adopting isostructural discrete octahedral cage geometries, were successfully synthesized under solvothermal conditions. These structures are all built up from the same pentavanadate {V5O9Cl} cluster connected by linear bidentate ligands (H2L1 = H2BDC, H2L2 = H2BDC-NH2, H2L3 = H2BDC-Br), respectively.
在溶剂热条件下成功合成了三种基于多氧钒酸盐的金属有机多面体（分别表示为VMOP-1、-2和-3），它们采用同构的离散八面体笼状几何结构。这些结构均由相同的五价钒酸盐{V5O9Cl}簇构建而成，分别通过线性双齿配体（H2L1 = H2BDC、H2L2 = H2BDC-NH2、H2L3 = H2BDC-Br）连接。
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