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2,5-双-（二苯基膦基）呋喃的晶体结构

Crystal structure of 2,5-bis-(di-phenyl-phosphan-yl)furan.

作者信息

Martínez de León Carla, Tlahuext Hugo, Grévy Jean-Michel

机构信息

Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001 Col. Chamilpa, CP 62209, Cuernavaca Mor., Mexico.

出版信息

Acta Crystallogr E Crystallogr Commun. 2015 Nov 11;71(Pt 12):o922-3. doi: 10.1107/S2056989015020964. eCollection 2015 Dec 1.

DOI:10.1107/S2056989015020964
PMID:26870529
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4719882/
Abstract

In the title compound, C28H22OP2, each of the P atoms has an almost perfect pyramidal geometry, with C-P-C angles varying from 100.63 (10) to 102.65 (9)°. In the crystal, neighbouring mol-ecules are linked via weak C-H⋯π inter-actions, forming supra-molecular chains along the b-axis direction.

摘要

在标题化合物C₂₈H₂₂OP₂中，每个磷原子都具有近乎完美的棱锥几何构型，C-P-C键角在100.63 (10)°至102.65 (9)°之间变化。在晶体中，相邻分子通过弱C-H⋯π相互作用相连，沿b轴方向形成超分子链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b11e/4719882/899e12546352/e-71-0o922-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b11e/4719882/545590361b0c/e-71-0o922-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b11e/4719882/899e12546352/e-71-0o922-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b11e/4719882/545590361b0c/e-71-0o922-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b11e/4719882/899e12546352/e-71-0o922-fig2.jpg

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