Mohamed Shaaban K, Mague Joel T, Akkurt Mehmet, Hassan Alaa A, Abdel-Aziz Ahmed T, Albayati Mustafa R
Faculty of Science & Engineering, School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD, England; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Acta Crystallogr E Crystallogr Commun. 2015 Nov 11;71(Pt 12):o924-5. doi: 10.1107/S2056989015021003. eCollection 2015 Dec 1.
In the title compound, C9H15N3S, the cyclo-pentyl ring adopts an envelope conformation with one of the methyl-ene C atoms as the flap. The thio-semicarbazide fragment is almost planar (r.m.s. deviation = 0.038 Å) and a short intra-molecular N-H⋯N contact occurs. In the crystal, mol-ecules are linked into helical (41 symmetry) chains propagating in [001] by N-H⋯N and N-H⋯S hydrogen bonds. A very weak C-H⋯S inter-action is also observed.
在标题化合物C₉H₁₅N₃S中，环戊基环呈信封式构象，其中一个亚甲基C原子为瓣。硫代氨基脲片段几乎是平面的（均方根偏差 = 0.038 Å），并存在短的分子内N-H⋯N接触。在晶体中，分子通过N-H⋯N和N-H⋯S氢键连接成沿[001]方向传播的螺旋（4¹对称）链。还观察到非常弱的C-H⋯S相互作用。
