2-氨基-4-（4-氯苯基）-1-（4-甲基苯基）-5-氧代-1,4,5,6,7,8-六氢喹啉-3-甲腈的晶体结构
Crystal structure of 2-amino-4-(4-chloro-phen-yl)-1-(4-methyl-phen-yl)-5-oxo-1,4,5,6,7,8-hexa-hydro-quinoline-3-carbo-nitrile.
作者信息
Mohamed Shaaban K, Akkurt Mehmet, Jasinski Jerry P, Allah Omyma A A Abd, Albayati Mustafa R
机构信息
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
出版信息
Acta Crystallogr E Crystallogr Commun. 2015 Nov 14;71(Pt 12):o949-50. doi: 10.1107/S2056989015021313. eCollection 2015 Dec 1.
In the title compound, C23H20ClN3O, each of the cyclo-hexene and 1,4-di-hydro-pyridine rings of the 1,4,5,6,7,8-hexa-hydro-quinoline ring system adopts a twisted-boat conformation. The dihedral angle between the two benzene rings is 11.52 (7)°. In the crystal, mol-ecules are linked through a pair of amino-nitrile N-H⋯N hydrogen bonds, forming inversion dimers. These assemble into a three-dimensional network via C-H⋯O and C-H⋯π inter-actions.
在标题化合物C₂₃H₂₀ClN₃O中，1,4,5,6,7,8-六氢喹啉环系中的环己烯环和1,4-二氢吡啶环均呈扭船构象。两个苯环之间的二面角为11.52 (7)°。在晶体中，分子通过一对氨基腈N-H⋯N氢键相连，形成倒转二聚体。这些通过C-H⋯O和C-H⋯π相互作用组装成三维网络。
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