Baylon Rebecca A L, Sun Junming, Martin Kevin J, Venkitasubramanian Padmesh, Wang Yong
The Gene & Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA 99164-2710, USA.
Archer Daniels Midland Company, 1001 N Brush College Road, Decatur, IL 62521, USA.
Chem Commun (Camb). 2016 Apr 11;52(28):4975-8. doi: 10.1039/c5cc10528e.
We report the direct conversion of mixed carboxylic acids to C-C olefins with up to 60 mol% carbon yield through cascade (cross) ketonization, (cross) aldolization and self-deoxygenation reactions. Co-feeding hydrogen provides an additional ketone hydrogenation/dehydration pathway to a wider range of olefins.
我们报道了通过级联（交叉）酮化、（交叉）羟醛缩合和自脱氧反应将混合羧酸直接转化为碳产率高达60 mol%的碳-碳烯烃。共进料氢气为更广泛的烯烃提供了额外的酮氢化/脱水途径。
