捕获分子溴：一种以 Br₂ 为连接体的一维溴铋酸盐配合物。
Trapping molecular bromine: a one-dimensional bromobismuthate complex with Br2 as a linker.
作者信息
Adonin S A, Gorokh I D, Abramov P A, Plyusnin P E, Sokolov M N, Fedin V P
机构信息
Nikolaev Institute of Inorganic Chemistry, 3 Lavrentieva Av., 630090 Novosibirsk, Russia.
出版信息
Dalton Trans. 2016 Mar 7;45(9):3691-3. doi: 10.1039/c5dt04464b. Epub 2016 Feb 1.
PMID:26905232
Abstract
The reaction between solid (NMP)n{[BiBr4]}n (1) (NMP = N-methylpyridinium) and Br2, generated in situ in HBr solution, results in the formation of (NMP)3[Bi2Br9]·Br2 (2). In the structure of 2, dibromine molecules connect discrete binuclear Bi2Br9 anions into an extended network. Complex 2 is thermally stable (up to 150 °C).
摘要
固体（NMP）n{[BiBr4]}n（1）（NMP = N-甲基吡啶鎓）与在HBr溶液中原位生成的Br2之间的反应，导致形成（NMP）3[Bi2Br9]·Br2（2）。在2的结构中，二溴分子将离散的双核Bi2Br9阴离子连接成一个扩展网络。配合物2热稳定性良好（高达150°C）。
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