Ullinger Heather L, Kennedy Marla J, Schneider William H, Miller Christopher M
Department of Civil Engineering, University of Akron, Akron, Ohio, United States of America.
PLoS One. 2016 Feb 23;11(2):e0149500. doi: 10.1371/journal.pone.0149500. eCollection 2016.
The Ohio Department of Transportation has more than 60 facilities without sewer access generating approximately 19 million gallons of winter maintenance wash water. Off-site disposal is costly, creating the need for sustainable management strategies. The objective of this study was to conduct an exploratory feasibility analysis to assess wash water disposal and potential reuse as brine. Based on a comprehensive literature review and relevant environmental chemistry, a sampling protocol consisting of 31 water quality constituents was utilized for monthly sampling at three geographically distinct Ohio Department of Transportation garages during the winter of 2012. Results were compared to local disposal and reuse guidance limits. Three constituents, including a maximum copper concentration of 858 ppb, exceeded disposal limits, and many constituents also failed to meet reuse limits. Some concentrations were orders of magnitude higher than reuse limits and suggest pre-treatment would be necessary if wash water were reused as brine. These water quality results, in conjunction with copper chemical equilibrium modeling, show pH and dissolved carbon both significantly impact the total dissolved copper concentration and should be measured to assess reuse potential. The sampling protocol and specific obstacles highlighted in this paper aid in the future development of sustainable wash water management strategies.
俄亥俄州交通运输部有60多个设施没有下水道接入,产生了约1900万加仑的冬季养护冲洗水。场外处理成本高昂,因此需要可持续的管理策略。本研究的目的是进行探索性可行性分析,以评估冲洗水的处理及作为盐水再利用的潜力。基于全面的文献综述和相关环境化学知识,在2012年冬季,采用了一个由31种水质成分组成的采样方案,对俄亥俄州三个地理位置不同的交通运输部车库进行月度采样。将结果与当地处理和再利用指导限值进行比较。三种成分超过了处理限值,其中铜的最高浓度为858 ppb,许多成分也未达到再利用限值。一些浓度比再利用限值高出几个数量级,这表明如果冲洗水作为盐水再利用,预处理是必要的。这些水质结果,结合铜化学平衡模型,表明pH值和溶解碳均对总溶解铜浓度有显著影响,应进行测量以评估再利用潜力。本文强调的采样方案和具体障碍有助于未来可持续冲洗水管理策略的发展。