Xu Xin, Pu Wen-hong, Shi Ya-fei, Yu Wen-bo, Zhang Shi-nan, Song Jian, Zhang Hao, He Shu, Yang Chang-zhu, Yang Jia-kuan
Huan Jing Ke Xue. 2015 Nov;36(11):4202-7.
The water content of dewatered sewage sludge can decrease at about 80% by traditional sludge dewatering technologies. High water content has negative impacts on the sequent sludge disposal with a stricter standard. The sulfate free radical SO4(*-), generated by activated persulfate, is a powerful oxidant. This article found that it could improve sludge dewatering properties by using the Fe2+ activated sodium persulfate (SPS). The results showed that when using Fe2+ 25.88 mg x g(-1) (based on dry sludge solid) and S2 O8(2-) 80 mg x g(-1) (the mole ratio of Fe2+ to S2 O8(2-) was 1.1 : 1) for sludge conditioning, it could reduce the capillary suction time (CST) and specific resistance to filtration (RSF) of sludge, increased the protein and ploysaccharide as well as the COD concentration in the filtrate. The further research showed that this method could change the zeta potential of sludge, increased the sludge particle specific surface area, and made flocs become a loose layered structure from dense clusters, which was beneficial to improve the sludge dewaterability.
通过传统的污泥脱水技术,脱水污泥的含水量可降低至约80%。高含水量对后续更严格标准的污泥处置有负面影响。过硫酸盐活化产生的硫酸根自由基SO4(*-)是一种强氧化剂。本文发现,使用Fe2+活化过硫酸钠(SPS)可以改善污泥脱水性能。结果表明,当使用25.88 mg x g(-1)的Fe2+(基于干污泥固体)和80 mg x g(-1)的S2O8(2-)(Fe2+与S2O8(2-)的摩尔比为1.1:1)进行污泥调理时,可降低污泥的毛细吸水时间(CST)和比过滤阻力(RSF),提高滤液中蛋白质、多糖以及COD的浓度。进一步研究表明,该方法可改变污泥的zeta电位,增加污泥颗粒比表面积,使絮体从致密团簇变为松散分层结构,有利于提高污泥脱水性能。