Wei Mei-Jie, Zang Hong-Ying, Zhou En-Long, Shao Kui-Zhan, Song Bai-Qiao, Wang Xin-Long, Su Zhong-Min
Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China.
Dalton Trans. 2016 Mar 28;45(12):4989-92. doi: 10.1039/c6dt00496b.
Assembly of cucurbit[6] and a {Cd2Ge8V12O48} cluster produced two rotaxane-shaped and polyrotaxane-shaped solids by changing the ratio of starting precursors in the system. The high oxygen density of the polyoxoanion surface provides active sites to extend a single rotaxane-shaped hybrid 1 to a 1D polyrotaxane-shaped hybrid 2. This construction strategy may afford an entirely new methodology for polyoxometalate-based hybrid chemistry.
通过改变体系中起始前驱体的比例，葫芦[6]与{Cd2Ge8V12O48}簇的组装产生了两种轮烷形状和聚轮烷形状的固体。聚氧阴离子表面的高氧密度提供了活性位点，可将单个轮烷形状的杂化物1扩展为一维聚轮烷形状的杂化物2。这种构建策略可能为基于多金属氧酸盐的杂化化学提供一种全新的方法。
