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用于有机化学降解的活化过硫酸盐:综述

Activated persulfate for organic chemical degradation: A review.

作者信息

Matzek Laura W, Carter Kimberly E

机构信息

Department of Civil and Environmental Engineering, University of Tennessee, 325 John D. Tickle Building, Knoxville, TN 37996-2313, USA.

Department of Civil and Environmental Engineering, University of Tennessee, 325 John D. Tickle Building, Knoxville, TN 37996-2313, USA.

出版信息

Chemosphere. 2016 May;151:178-88. doi: 10.1016/j.chemosphere.2016.02.055. Epub 2016 Mar 15.

Abstract

Activated persulfate reactions have widespread application for groundwater and environmental remediation, as many of these reactions involve destruction of environmental contaminants. Within the last five years, knowledge of activated persulfate degradation reactions has grown to include novel means of activating persulfate for enhanced removal of organic species. These current studies cover a long list of organic analytes, including pharmaceuticals, pesticides, halogenated compounds and dyes. An extensive review of recently published experimental parameters and results for the destruction of organic compounds via activated persulfate is presented. Focus is placed on emerging methodologies and manipulation of traditional activation techniques. Knowledge gaps are identified and discussed, as despite the number of publications on this subject, more broad-reaching guidelines are needed for optimizing applications of activated persulfate in water treatment.

摘要

活化过硫酸盐反应在地下水和环境修复方面有着广泛应用,因为其中许多反应涉及对环境污染物的破坏。在过去五年中,关于活化过硫酸盐降解反应的知识不断增长,已涵盖了活化过硫酸盐以增强有机物种去除效果的新方法。这些当前研究涉及一长串有机分析物,包括药物、农药、卤代化合物和染料。本文对最近发表的通过活化过硫酸盐破坏有机化合物的实验参数和结果进行了广泛综述。重点关注新兴方法以及传统活化技术的操控。尽管关于该主题的出版物数量众多,但仍需更具广泛适用性的指南来优化活化过硫酸盐在水处理中的应用,文中对此知识空白进行了识别和讨论。

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