新型基于二甘油的环保型非异氰酸酯聚（羟基脲烷）的合成与表征数据。

Data on synthesis and characterization of new diglycerol based environmentally friendly non-isocyanate poly(hydroxyurethanes).

作者信息

Tryznowski Mariusz, Świderska Aleksandra, Żołek-Tryznowska Zuzanna, Gołofit Tomasz, Parzuchowski Paweł G

机构信息

Warsaw University of Technology, Faculty of Chemistry, Poland.

Warsaw University of Technology, Faculty of Production Engineering, Poland.

出版信息

Data Brief. 2015 Nov 22;6:77-82. doi: 10.1016/j.dib.2015.11.034. eCollection 2016 Mar.

DOI:10.1016/j.dib.2015.11.034

PMID:26958623

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4773383/

Abstract

This article contains original experimental data, figures and methods to the preparation of non-isocyanate poly(hydroxyurethanes) by an environmentally friendly method without the use of toxic phosgene and isocyanates from bis(2,3-dihydroxypropyl)ether dicarbonate and various diamines (Tryznowski et al., Submitted for publication) [1]. Bis(2,3-dihydroxypropyl)ether dicarbonate was obtained from a one-step procedure from commercially available diglycerol. The product was characterized by (1)H NMR, (13)C NMR, and FTIR spectroscopies and for the first time by X-Ray diffraction measurements. Then, the bis(cyclic carbonate) monomer was used as a precursor for the synthesis of various NIPUs. The NIPUs were prepared in a non-solvent process. Spectral and thermal properties of the NIPUs are compered. Here we give the procedure in order to perform bis(2,3-dihydroxypropyl)ether dicarbonate with high yield and the procedure NIPU synthesis and the complete set of monomer and NIPU analysis ((1)H NMR, (13)C NMR, FTIR, X-Ray).

摘要

本文包含通过环保方法制备非异氰酸酯聚（羟基脲烷）的原始实验数据、图表和方法，该方法不使用有毒的光气和异氰酸酯，而是以双（2,3-二羟基丙基）醚二碳酸酯和各种二胺为原料（特里兹诺夫斯基等人，已提交发表）[1]。双（2,3-二羟基丙基）醚二碳酸酯由市售二甘油通过一步法制备。该产物通过（1）H NMR、（13）C NMR和FTIR光谱进行表征，并且首次通过X射线衍射测量进行表征。然后，将双（环状碳酸酯）单体用作合成各种非异氰酸酯聚脲烷（NIPUs）的前体。NIPUs是在非溶剂过程中制备的。对NIPUs的光谱和热性能进行了比较。在此，我们给出了高产率制备双（2,3-二羟基丙基）醚二碳酸酯的步骤、NIPU合成步骤以及单体和NIPU的全套分析方法（（1）H NMR、（13）C NMR、FTIR、X射线）。