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超分子凝胶性质的表面定向调控

Surface-directed modulation of supramolecular gel properties.

作者信息

Angelerou Maria Galini Faidra, Sabri Akmal, Creasey Rhiannon, Angelerou Polyxeni, Marlow Maria, Zelzer Mischa

机构信息

University of Nottingham, School of Pharmacy, Nottingham NG7 2RD, UK.

School of Chemistry, University of Queensland, St Lucia, 4067, Australia.

出版信息

Chem Commun (Camb). 2016 Mar 21;52(23):4298-300. doi: 10.1039/c6cc00292g.

DOI:10.1039/c6cc00292g
PMID:26960905
Abstract

Supramolecular materials are widely studied and used for a variety of applications; in most applications, these materials are in contact with surfaces of other materials. Whilst much focus has been placed on elucidating factors that affect supramolecular material properties, the influence of the material surface on gel formation is poorly characterised. Here, we demonstrate that surface properties directly affect the fibre architecture and mechanical properties of self-assembled cytidine based gel films.

摘要

超分子材料被广泛研究并应用于各种领域;在大多数应用中,这些材料会与其他材料的表面接触。虽然人们已经非常关注阐明影响超分子材料性能的因素,但材料表面对凝胶形成的影响却鲜有研究。在此,我们证明表面性质直接影响基于胞嘧啶核苷自组装凝胶膜的纤维结构和机械性能。

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1
Surface-directed modulation of supramolecular gel properties.超分子凝胶性质的表面定向调控
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引用本文的文献

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Personal Perspective on Understanding Low Molecular Weight Gels.关于理解低分子凝胶的个人观点。
J Am Chem Soc. 2022 Jun 29;144(25):11047-11053. doi: 10.1021/jacs.2c02096. Epub 2022 Jun 17.
2
Surface-controlled spatially heterogeneous physical properties of a supramolecular gel with homogeneous chemical composition.具有均匀化学组成的超分子凝胶的表面控制空间异质物理性质。
Chem Sci. 2021 Oct 11;12(42):14260-14269. doi: 10.1039/d1sc04671c. eCollection 2021 Nov 3.
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Does Drying Affect Gel Networks?干燥会影响凝胶网络吗?
Gels. 2018 Apr 3;4(2):32. doi: 10.3390/gels4020032.
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Supramolecular Nucleoside-Based Gel: Molecular Dynamics Simulation and Characterization of Its Nanoarchitecture and Self-Assembly Mechanism.基于超分子核苷的凝胶:其纳米结构和自组装机制的分子动力学模拟与表征。
Langmuir. 2018 Jun 12;34(23):6912-6921. doi: 10.1021/acs.langmuir.8b00646. Epub 2018 May 29.