Yan Xiao-Wei, Haji-Hasani Ensieh, Morsali Ali
College of Chemical and Biological Engineering, Hezhou University, Hezhou 542800, China.
Department of Chemistry, Payame Noor University, Abhar, Zanjan, Islamic Republic of Iran.
Ultrason Sonochem. 2016 Jul;31:129-34. doi: 10.1016/j.ultsonch.2015.11.014. Epub 2015 Nov 26.
Two new bismuth(III) coordination supramolecular polymers, {Bi2(Hbpp)(bpp)(μ-I)2I6·MeOH}n (1) and [Bi(Hbpp)(Br4)] (2), (bpp=1,3-di(pyridin-4-yl)propane) were prepared and were structurally characterized by single crystal X-ray diffraction. Single crystalline one-dimensional materials were prepared using a heat gradient applied a solution of the reagents using the branched tube method. The structural determination by single crystal X-ray crystallography shows that compounds 1 and 2 form monoclinic polymers with symmetry space group P21 in the solid state. These new nanostructured Bi(III) supramolecular compounds, {Bi2(Hbpp)(bpp)(μ-I)2I6·MeOH} (1) and [Bi(Hbpp)(Br4)] (2), were also synthesized by sonochemical method. The nanostructures were characterized by Field Emission-scanning electron microscopy (FE-SEM), powder X-ray diffraction (PXRD) and IR spectroscopy.
