黑磷的表面配位使其具有良好的空气和水稳定性。
Surface Coordination of Black Phosphorus for Robust Air and Water Stability.
机构信息
Institute of Biomedicine and Biotechnology, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, P.R. China.
Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China.
出版信息
Angew Chem Int Ed Engl. 2016 Apr 11;55(16):5003-7. doi: 10.1002/anie.201512038. Epub 2016 Mar 10.
A titanium sulfonate ligand is synthesized for surface coordination of black phosphorus (BP). In contrast to serious degradation observed from the bare BP, the BP after surface coordination exhibits excellent stability during dispersion in water and exposure to air for a long period of time, thereby significantly extending the lifetime and spurring broader application of BP.
合成了一种钛磺酸盐配体用于黑磷（BP）的表面配位。与裸 BP 观察到的严重降解相比，表面配位后的 BP 在水中分散和长时间暴露于空气中时表现出优异的稳定性，从而显著延长了 BP 的寿命并推动了其更广泛的应用。
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