Ebrahim-Alkhalil Ahmed, Zhang Zhen-Qi, Gong Tian-Jun, Su Wei, Lu Xiao-Yu, Xiao Bin, Fu Yao
Hefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of China, Hefei 230026, China.
Chem Commun (Camb). 2016 Apr 7;52(27):4891-3. doi: 10.1039/c5cc09817c. Epub 2016 Mar 14.
Herein, we describe a novel copper-catalyzed epoxide opening reaction with gem-diborylmethane. Aliphatic, aromatic epoxides as well as aziridines are converted to the corresponding γ-pinacolboronate alcohols or amines in moderate to excellent yields. This new reaction provides beneficial applications for classic epoxide substrates as well as interesting gem-diborylalkane reagents.
在此，我们描述了一种新型的铜催化的环氧化物与偕二硼基甲烷的开环反应。脂肪族、芳香族环氧化物以及氮丙啶可转化为相应的γ-频哪醇硼酸酯醇或胺，产率适中至优异。这种新反应为经典的环氧化物底物以及有趣的偕二硼基烷烃试剂提供了有益的应用。
