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面式三羰基（环己基异腈-κC）（喹啉-2-羧酸根-κ(2)N，O）铼（I）的晶体结构

Crystal structure of fac-tricarbon-yl(cyclo-hexyl isocyanide-κC)(quinoline-2-carboxyl-ato-κ(2) N,O)rhenium(I).

作者信息

Triantis Charalampos, Shegani Antonio, Kiritsis Christos, Raptopoulou Catherine, Psycharis Vassilis, Pelecanou Maria, Pirmettis Ioannis, Papadopoulos Minas

机构信息

Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece.

Institute of Nanoscience and Nanotechnology, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece.

出版信息

Acta Crystallogr E Crystallogr Commun. 2016 Feb 17;72(Pt 3):358-62. doi: 10.1107/S2056989016002206. eCollection 2016 Mar 1.

DOI:10.1107/S2056989016002206
PMID:27006808
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4778812/
Abstract

In the title compound, [Re(C10H6NO2)(C7H11N)(CO)3], the Re(I) atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C4NO coordination sphere is distorted octa-hedral. A lengthening of the axial Re-CO bond trans to the isocyanide ligand is indicative of the trans effect. Individual complexes are stacked into rods parallel to [001] through displaced π-π inter-actions. Weak C-H⋯O hydrogen-bonding inter-actions between the rods lead to the formation of layers parallel to (010). These layers are stacked along [010] by C-H⋯H-C van der Waals contacts.

摘要

在标题化合物[Re(C₁₀H₆NO₂)(C₇H₁₁N)(CO)₃]中，Re(I)原子由三个呈面式排列的羰基配体配位，并且分别由螯合喹哪啶阴离子和单齿异腈配体中的N、O和C原子配位。由此形成的C₄NO配位球呈扭曲八面体形状。与异腈配体反位的轴向Re-CO键伸长表明了反位效应。单个配合物通过错位的π-π相互作用堆积成平行于[001]的棒状结构。棒状结构之间的弱C-H⋯O氢键相互作用导致形成平行于(010)的层。这些层通过C-H⋯H-C范德华接触沿[010]堆叠。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/f372444610f2/e-72-00358-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/bd169f9ce7a3/e-72-00358-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/0e36f25f33c8/e-72-00358-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/1ddfc3bf2a3a/e-72-00358-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/fd89196e3e14/e-72-00358-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/2680f175e526/e-72-00358-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/f372444610f2/e-72-00358-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/bd169f9ce7a3/e-72-00358-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/0e36f25f33c8/e-72-00358-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/1ddfc3bf2a3a/e-72-00358-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/fd89196e3e14/e-72-00358-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/2680f175e526/e-72-00358-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af4c/4778812/f372444610f2/e-72-00358-fig6.jpg

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本文引用的文献

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2
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ACS Chem Biol. 2014 Oct 17;9(10):2180-93. doi: 10.1021/cb500528c. Epub 2014 Aug 25.
3
Luminescence modulations of rhenium tricarbonyl complexes induced by structural variations.
结构变化诱导的三羰基铼配合物的发光调制
Inorg Chem. 2014 Jun 16;53(12):6204-23. doi: 10.1021/ic5007007. Epub 2014 Jun 6.
4
Rhenium and technetium bi- and tricarbonyl complexes in a new strategy for biomolecule incorporation using click chemistry.铼和锝的双羰基和三羰基配合物在一种使用点击化学将生物分子纳入的新策略中。
Dalton Trans. 2014 May 21;43(19):6998-7001. doi: 10.1039/c4dt00684d. Epub 2014 Apr 7.
5
The Cambridge Structural Database in retrospect and prospect.《剑桥结构数据库的回顾与展望》
Angew Chem Int Ed Engl. 2014 Jan 13;53(3):662-71. doi: 10.1002/anie.201306438. Epub 2014 Jan 2.
6
Curcumin as the OO bidentate ligand in "2 + 1" complexes with the [M(CO)3]+ (M = Re, 99mTc) tricarbonyl core for radiodiagnostic applications.姜黄素作为“2+1”配合物中的 OO 双齿配体，与[M(CO)3]+（M = Re、99mTc）三羰基核配合，用于放射诊断应用。
Inorg Chem. 2011 Feb 21;50(4):1295-303. doi: 10.1021/ic102228u. Epub 2011 Jan 21.
7
Aqua-tricarbon-yl(4-carboxy-pyridine-2-carboxyl-ato-κN,O)rhenium(I).水合三羰基（4-羧基吡啶-2-羧酸根合-κN,O）铼（I）
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Chem Biol Drug Des. 2009 Jul;74(1):80-6. doi: 10.1111/j.1747-0285.2009.00831.x.
9
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