一种三维手风琴状金属有机框架：合成及其在表面上的非常规取向生长。
A three-dimensional accordion-like metal-organic framework: synthesis and unconventional oriented growth on a surface.
作者信息
Haraguchi Tomoyuki, Otsubo Kazuya, Sakata Osami, Kawaguchi Shogo, Fujiwara Akihiko, Kitagawa Hiroshi
机构信息
Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan.
出版信息
Chem Commun (Camb). 2016 May 1;52(35):6017-20. doi: 10.1039/c6cc00056h. Epub 2016 Apr 11.
We describe the synthesis and sorption properties of a new metal-organic framework (MOF), Fe(H2O)2(bpy)[Pt(CN)4]·H2O (bpy = 4,4'-bipyridine), with a three-dimensional accordion-like structure. Although crystalline oriented MOF thin films reported to date have been mainly limited to a layer-type structure, we succeeded in the fabrication of its crystalline oriented thin film.
我们描述了一种具有三维手风琴状结构的新型金属有机框架（MOF），即Fe(H₂O)₂(bpy)[Pt(CN)₄]·H₂O（bpy = 4,4'-联吡啶）的合成及吸附特性。尽管迄今为止报道的晶体取向MOF薄膜主要局限于层状结构，但我们成功制备了其晶体取向薄膜。
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