Ciulu Marco, Spano Nadia, Pilo Maria I, Sanna Gavino
Dipartimento di Chimica e Farmacia, Università degli Studi di Sassari, via Vienna 2, 07100 Sassari, Italy.
Molecules. 2016 Apr 8;21(4):451. doi: 10.3390/molecules21040451.
Honey is one of the most renowned natural foods. Its composition is extremely variable, depending on its botanical and geographical origins, and the abundant presence of functional compounds has contributed to the increased worldwide interest is this foodstuff. In particular, great attention has been paid by the scientific community towards classes of compounds like phenolic compounds, due to their capability to act as markers of unifloral honey origin. In this contribution the most recent progress in the assessment of new analytical procedures aimed at the definition of the qualitative and quantitative profile of phenolic compounds of honey have been highlighted. A special emphasis has been placed on the innovative aspects concerning the extraction procedures, along with the most recent strategies proposed for the analysis of phenolic compounds. Moreover, the centrality of validation procedures has been claimed and extensively discussed in order to ensure the fitness-for-purpose of the proposed analytical methods. In addition, the exploitation of the phenolic profile as a tool for the classification of the botanical and geographical origin has been described, pointing out the usefulness of chemometrics in the interpretation of data sets originating from the analysis of polyphenols. Finally, recent results in concerning the evaluation of the antioxidant properties of unifloral honeys and the development of new analytical approaches aimed at measuring this parameter have been reviewed.
蜂蜜是最著名的天然食品之一。其成分极为多样,取决于其植物来源和地理来源,并且功能性化合物的大量存在促使全球对这种食品的兴趣增加。特别是,科学界对酚类化合物等化合物类别给予了极大关注,因为它们能够作为单花蜂蜜来源的标志物。在本论文中,着重介绍了旨在确定蜂蜜中酚类化合物定性和定量特征的新分析方法评估方面的最新进展。特别强调了提取程序的创新方面,以及针对酚类化合物分析提出的最新策略。此外,为确保所提出分析方法的适用性,对验证程序的核心地位进行了主张并进行了广泛讨论。此外,还描述了利用酚类特征作为植物和地理来源分类工具的情况,指出了化学计量学在解释源自多酚分析的数据集方面的有用性。最后,综述了单花蜂蜜抗氧化性能评估的最新结果以及旨在测量该参数的新分析方法的开发情况。