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利用胶-纳米填料增强各向异性取向颗粒间的界面结合用于先进锂离子电池正极。

Enhancing Interfacial Bonding between Anisotropically Oriented Grains Using a Glue-Nanofiller for Advanced Li-Ion Battery Cathode.

机构信息

Department of Energy Engineering, School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798, Republic of Korea.

出版信息

Adv Mater. 2016 Jun;28(23):4705-12. doi: 10.1002/adma.201506256. Epub 2016 Apr 13.

DOI:10.1002/adma.201506256
PMID:27074141
Abstract

Formation of a glue-nanofiller layer between grains, consisting of a middle-temperature spinel-like Lix CoO2 phase, reinforces the strength of the incoherent interfacial binding between anisotropically oriented grains by enhancing the face-to-face adhesion strength. The cathode treated with the glue-layer exhibits steady cycling performance at both room-temperature and 60 °C. These results represent a step forward in advanced lithium-ion batteries via simple cathode coating.

摘要

在晶粒之间形成了一层胶态纳米填料层,由中温尖晶石状 LixCoO2 相组成,通过提高面对面的黏附强度来增强各向异性取向晶粒之间的非晶态界面结合强度。经胶层处理的阴极在室温及 60°C 下均表现出稳定的循环性能。这些结果通过简单的阴极涂覆,代表了先进锂离子电池的一个进步。

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