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选择合适的工具:红外衰减全反射附件的分析性能比较

Selecting the Right Tool: Comparison of the Analytical Performance of Infrared Attenuated Total Reflection Accessories.

作者信息

Schädle Thomas, Mizaikoff Boris

机构信息

Institute of Analytical and Bioanalytical Chemistry, University of Ulm, Ulm, Germany.

Institute of Analytical and Bioanalytical Chemistry, University of Ulm, Ulm, Germany

出版信息

Appl Spectrosc. 2016 Jun;70(6):1072-9. doi: 10.1177/0003702816641574. Epub 2016 Apr 18.

DOI:10.1177/0003702816641574
PMID:27091901
Abstract

The analytical performance of four commercially available infrared attenuated total reflection (IR-ATR) accessories with various ATR waveguide materials has been analyzed and evaluated using acetate, CO2, and CO3 (2-) solutions. Calibration functions have been established to determine and compare analytically relevant parameters such as sensitivity, signal-to-noise ratio (SNR), and efficiency. The obtained parameters were further analyzed to support conclusions on the differences in performance of the individual IR-ATR accessories.

摘要

使用乙酸盐、二氧化碳和碳酸根(2-)溶液,对四种采用不同衰减全反射(ATR)波导材料的市售红外衰减全反射(IR-ATR)附件的分析性能进行了分析和评估。已建立校准函数,以确定和比较诸如灵敏度、信噪比(SNR)和效率等分析相关参数。对获得的参数进行了进一步分析,以支持有关各个IR-ATR附件性能差异的结论。

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