Tuning phase structures of a symmetrical diblock copolymer with a patterned electric field.

Electric fields can induce the orientation of the phase interfaces of block copolymers and provide a potential method to tune polymer phase structures for nanomaterial manufacture. In this work, we applied self-consistent field theory to study the self-assembly of a diblock copolymer confined between two parallel neutral substrates on which a set of electrodes was imposed to form a patterned electric field. The results showed that an alternatively distributed electric field can induce the formation of a parallel lamellar phase structure, which exists stably only in the system with selective substrates. The phase structure was proved to be sensitive to the characteristics of the electric field distribution, such as the strength of the electric field, the size and position of the electrodes, and the corresponding phase diagram was calculated in detail. The transition pathway of the phase structure from the perpendicular layered phase to the parallel layered phase was further analysed using the minimum energy path method. It is shown that the path and the active energy barrier of the phase transition depend on the electric field strength. Compound electric field patterns that can be designed to control the formation of novel and complex microphase structures were also examined.