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辣木种子提取物作为一种清洁混凝剂与明矾及辣木-明矾复合混凝剂用于去除纺织废水中直接染料的比较。

Comparison of Moringa stenopetala seed extract as a clean coagulant with Alum and Moringa stenopetala-Alum hybrid coagulant to remove direct dye from Textile Wastewater.

作者信息

Dalvand Arash, Gholibegloo Elham, Ganjali Mohammad Reza, Golchinpoor Najmeh, Khazaei Mohammad, Kamani Hossein, Hosseini Sara Sadat, Mahvi Amir Hossein

机构信息

Students' Scientific Research Center (SSRC), Tehran University of Medical Sciences, Tehran, Iran.

Department of Environmental Health Engineering, School of Public Health, Tehran University of Medical Sciences, Tehran, Iran.

出版信息

Environ Sci Pollut Res Int. 2016 Aug;23(16):16396-405. doi: 10.1007/s11356-016-6708-z. Epub 2016 May 10.

Abstract

In this study, the efficiency of Moringa stenopetala seed extract was compared with alum and M. stenopetala-alum hybrid coagulant to remove Direct Red 23 azo dye from textile wastewater. The effects of parameters such as pH, coagulant dose, type of salt used for the extraction of coagulant and initial dye concentration on dye removal efficiency were investigated. Moreover, the existing functional groups on the structure of M. stenopetala coagulant (MSC) were determined by Fourier transform infrared spectroscopy, and the morphology of sludge produced by MSC, alum, and hybrid coagulant was characterized by scanning electron microscopy. Ninhydrin test was also used to determine the quantity of primary amines in the MSC and Moringa oleifera coagulant (MOC). According to the results, with increasing the coagulant dose and decreasing the initial dye concentration, dye removal efficiency has increased. The maximum dye removal of 98.5, 98.2, and 98.3 % were obtained by using 240, 120, and 80 mg/L MSC, alum and hybrid coagulant at pH 7, respectively. The results also showed MSC was much more effective than MOC for dye removal. The volume of sludge produced by MSC was one fourth and half of those produced by alum and hybrid coagulant, respectively. Based on the results, hybrid coagulant was the most efficient coagulant for direct dye removal from colored wastewater.

摘要

在本研究中,比较了狭瓣辣木籽提取物与明矾以及狭瓣辣木 - 明矾复合混凝剂从纺织废水中去除直接红23偶氮染料的效率。研究了pH值、混凝剂剂量、用于提取混凝剂的盐类型以及初始染料浓度等参数对染料去除效率的影响。此外,通过傅里叶变换红外光谱法测定了狭瓣辣木混凝剂(MSC)结构上现有的官能团,并通过扫描电子显微镜对MSC、明矾和复合混凝剂产生的污泥形态进行了表征。茚三酮试验也用于测定MSC和辣木籽混凝剂(MOC)中伯胺的含量。结果表明,随着混凝剂剂量的增加和初始染料浓度的降低,染料去除效率提高。在pH值为7时,分别使用240、120和80mg/L的MSC、明矾和复合混凝剂,染料最大去除率分别为98.5%、98.2%和98.3%。结果还表明,MSC在染料去除方面比MOC更有效。MSC产生的污泥量分别是明矾和复合混凝剂产生污泥量的四分之一和二分之一。基于这些结果,复合混凝剂是从有色废水中去除直接染料最有效的混凝剂。

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