三齿膦配位铜（I）配合物的平衡双发射用于高效黄光 OLEDs。
Balanced Dual Emissions from Tridentate Phosphine-Coordinate Copper(I) Complexes toward Highly Efficient Yellow OLEDs.
机构信息
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education and School of Chemistry and Material Science, Heilongjiang University, 74 Xuefu Road, Harbin, 150080, P. R. China.
Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing, 211816, P. R. China.
出版信息
Adv Mater. 2016 Jul;28(28):5975-9. doi: 10.1002/adma.201600487. Epub 2016 May 11.
Dual emissive copper(I) halide complexes TTPPCuX (X = Cl, Br, I) with a triphosphine ligand and stable tetrahedral geometries are constructed, in which TTPPCuI successfully achieves the balanced dual thermally activated delayed fluorescence and phosphorescence (PH) emissions with PH fraction of 39% at ambient temperature, supporting the equal triplet exciton reallocation for the state-of-the-art device performance.
具有三磷配体和稳定四面体几何形状的双发射铜（I）卤化物配合物 TTPPCuX（X = Cl，Br，I）被构建，其中 TTPPCuI 在环境温度下成功实现了平衡的双热激活延迟荧光和磷光（PH）发射，具有 39%的 PH 分数，支持三重态激子再分配，以实现最先进的器件性能。
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