紫外光介导的烯烃与三氟甲磺酸钠的双官能化反应：三氟甲基菲和蒽醌衍生物的合成
UV light-mediated difunctionalization of alkenes with CF3SO2Na: synthesis of trifluoromethyl phenanthrene and anthrone derivatives.
作者信息
Li Bing, Fan Dan, Yang Chao, Xia Wujiong
机构信息
State Key Lab of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150080, China.
出版信息
Org Biomol Chem. 2016 Jun 21;14(23):5293-7. doi: 10.1039/c6ob00912c. Epub 2016 May 20.
PMID:27206267
Abstract
A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF3SO2Na was developed. This strategy realized the direct formation of Csp(3)-CF3 and C-C bonds through a proposed tandem radical cyclization process, which produced a variety of phenanthrene and anthrone derivatives in moderate yields.
摘要
开发了一种无金属且经济高效的通过CF3SO2Na对烯烃进行紫外光介导的双官能化反应的方案。该策略通过提出的串联自由基环化过程实现了Csp(3)-CF3和C-C键的直接形成，以中等产率得到了多种菲和蒽醌衍生物。
Zotero 插件