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基于近红外光谱结合Adaboost和光谱回归判别分析的固体发酵过程状态识别

[State Recognition of Solid Fermentation Process Based on Near Infrared Spectroscopy with Adaboost and Spectral Regression Discriminant Analysis].

作者信息

Yu Shuang, Liu Guo-hai, Xia Rong-sheng, Jiang Hui

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2016 Jan;36(1):51-4.

Abstract

In order to achieve the rapid monitoring of process state of solid state fermentation (SSF), this study attempted to qualitative identification of process state of SSF of feed protein by use of Fourier transform near infrared (FT-NIR) spectroscopy analysis technique. Even more specifically, the FT-NIR spectroscopy combined with Adaboost-SRDA-NN integrated learning algorithm as an ideal analysis tool was used to accurately and rapidly monitor chemical and physical changes in SSF of feed protein without the need for chemical analysis. Firstly, the raw spectra of all the 140 fermentation samples obtained were collected by use of Fourier transform near infrared spectrometer (Antaris II), and the raw spectra obtained were preprocessed by use of standard normal variate transformation (SNV) spectral preprocessing algorithm. Thereafter, the characteristic information of the preprocessed spectra was extracted by use of spectral regression discriminant analysis (SRDA). Finally, nearest neighbors (NN) algorithm as a basic classifier was selected and building state recognition model to identify different fermentation samples in the validation set. Experimental results showed as follows: the SRDA-NN model revealed its superior performance by compared with other two different NN models, which were developed by use of the feature information form principal component analysis (PCA) and linear discriminant analysis (LDA), and the correct recognition rate of SRDA-NN model achieved 94.28% in the validation set. In this work, in order to further improve the recognition accuracy of the final model, Adaboost-SRDA-NN ensemble learning algorithm was proposed by integrated the Adaboost and SRDA-NN methods, and the presented algorithm was used to construct the online monitoring model of process state of SSF of feed protein. Experimental results showed as follows: the prediction performance of SRDA-NN model has been further enhanced by use of Adaboost lifting algorithm, and the correct recognition rate of the Adaboost-SRDA-NN model achieved 100% in the validation set. The overall results demonstrate that SRDA algorithm can effectively achieve the spectral feature information extraction to the spectral dimension reduction in model calibration process of qualitative analysis of NIR spectroscopy. In addition, the Adaboost lifting algorithm can improve the classification accuracy of the final model. The results obtained in this work can provide research foundation for developing online monitoring instruments for the monitoring of SSF process.

摘要

为实现固态发酵(SSF)过程状态的快速监测,本研究尝试利用傅里叶变换近红外(FT-NIR)光谱分析技术对饲料蛋白质固态发酵的过程状态进行定性识别。更具体地说,将FT-NIR光谱与Adaboost-SRDA-NN集成学习算法相结合,作为一种理想的分析工具,用于准确、快速地监测饲料蛋白质固态发酵过程中的化学和物理变化,而无需进行化学分析。首先,使用傅里叶变换近红外光谱仪(Antaris II)收集获得的140个发酵样品的原始光谱,并使用标准正态变量变换(SNV)光谱预处理算法对获得的原始光谱进行预处理。此后,使用光谱回归判别分析(SRDA)提取预处理光谱的特征信息。最后,选择最近邻(NN)算法作为基本分类器,构建状态识别模型以识别验证集中的不同发酵样品。实验结果如下:与使用主成分分析(PCA)和线性判别分析(LDA)的特征信息开发的其他两种不同的NN模型相比,SRDA-NN模型表现出卓越的性能,且SRDA-NN模型在验证集中的正确识别率达到了94.28%。在本工作中,为进一步提高最终模型的识别精度,通过集成Adaboost和SRDA-NN方法提出了Adaboost-SRDA-NN集成学习算法,并使用该算法构建饲料蛋白质固态发酵过程状态的在线监测模型。实验结果如下:通过使用Adaboost提升算法,SRDA-NN模型的预测性能得到了进一步增强,且Adaboost-SRDA-NN模型在验证集中的正确识别率达到了100%。总体结果表明,SRDA算法能够在近红外光谱定性分析的模型校准过程中有效地实现光谱特征信息提取和光谱降维。此外,Adaboost提升算法能够提高最终模型的分类精度。本工作获得的结果可为开发用于监测固态发酵过程的在线监测仪器提供研究基础。

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