Department of Chemical Engineering, Massachusetts Institute of Technology, 77, Massachusetts Avenue, Cambridge, MA 02139, USA.
Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, 8093 Zurich, Switzerland.
Adv Colloid Interface Sci. 2016 Sep;235:1-13. doi: 10.1016/j.cis.2016.05.002. Epub 2016 May 10.
The present work aims at reviewing our current understanding of fractal structures in the frame of colloid aggregation as well as the possibility they offer to produce novel structured materials. In particular, the existing techniques to measure and compute the fractal dimension df are critically discussed based on the cases of organic/inorganic particles and proteins. Then the aggregation conditions affecting df are thoroughly analyzed, pointing out the most recent literature findings and the limitations of our current understanding. Finally, the importance of the fractal dimension in applications is discussed along with possible directions for the production of new structured materials.
本文旨在回顾胶体聚集中分形结构的现有认识,以及它们在制备新型结构材料方面的可能性。特别是,基于有机/无机颗粒和蛋白质的情况,对现有的测量和计算分形维数 df 的技术进行了批判性讨论。然后,彻底分析了影响 df 的聚集条件,指出了最新文献的发现和我们现有认识的局限性。最后,讨论了分形维数在应用中的重要性以及制备新型结构材料的可能方向。