Surendra T V, Roopan Selvaraj Mohana
Chemistry of Heterocycles & Natural Product Research Laboratory, Department of Chemistry, School of Advanced Sciences, VIT University, Vellore 632 014, Tamilnadu, India.
Chemistry of Heterocycles & Natural Product Research Laboratory, Department of Chemistry, School of Advanced Sciences, VIT University, Vellore 632 014, Tamilnadu, India.
J Photochem Photobiol B. 2016 Aug;161:122-8. doi: 10.1016/j.jphotobiol.2016.05.019. Epub 2016 May 20.
Biosynthetic methods are alternative approaches which are much safer than the normal techniques (physical and chemical) used for the methods for synthesis of metal nanoparticles. The benefits are sample as it is economic and environment friendly. Herein present investigation, we have reported a microwave mediated eco-friendly synthetic approach for preparing cerium oxide (CeO2) nanoparticles. Here, we used Moringa oleifera peel as the stabilizing and reducing agent towards synthesize of Ce2O NPs via microwave irradiation. The NPs were further characterized using UV-Vis, FT-IR, XRD and HR-TEM techniques. The FTIR analysis confirmed the phytochemical involvement in NPs stabilization. The crystallinity of CeO2 nanoparticles are well demonstrated through X-ray Diffraction and HR-TEM. The TEM images reveal the spherical shape of the CeO2 NPs having an average size of 45nm. Additionally, these CeO2 NPs were used successfully as a catalyst in the degradation of the dye, crystal violet. Also the antibacterial activity of the synthesized CeO2 NPs was evaluated using Staphylococcus aureus (Gram positive bacteria) and Escherichia coli (Gram negative bacteria). CeO2 NPs showed better activity on E. coli than S. aureus. We have demonstrated an eco-friendly preparation of CeO2 nanoparticles, a good photocatalyst and having better antibacterial properties.
生物合成方法是一种替代方法,比用于合成金属纳米颗粒的常规技术(物理和化学技术)安全得多。其优点显而易见,因为它经济且环保。在本研究中,我们报道了一种微波介导的环保合成方法来制备氧化铈(CeO₂)纳米颗粒。在此,我们使用辣木果皮作为稳定剂和还原剂,通过微波辐射合成Ce₂O NPs。使用紫外可见光谱、傅里叶变换红外光谱、X射线衍射和高分辨透射电子显微镜技术对纳米颗粒进行了进一步表征。傅里叶变换红外光谱分析证实了植物化学物质参与了纳米颗粒的稳定化。通过X射线衍射和高分辨透射电子显微镜很好地证明了氧化铈纳米颗粒的结晶度。透射电子显微镜图像显示氧化铈纳米颗粒呈球形,平均尺寸为45nm。此外,这些氧化铈纳米颗粒成功地用作降解染料结晶紫的催化剂。还使用金黄色葡萄球菌(革兰氏阳性菌)和大肠杆菌(革兰氏阴性菌)评估了合成的氧化铈纳米颗粒的抗菌活性。氧化铈纳米颗粒对大肠杆菌的活性比对金黄色葡萄球菌的活性更好。我们展示了一种环保的氧化铈纳米颗粒制备方法,它是一种良好的光催化剂,具有更好的抗菌性能。