Linares Hernández Ivonne, Barrera Díaz Carlos, Valdés Cerecero Mario, Almazán Sánchez Perla Tatiana, Castañeda Juárez Monserrat, Lugo Lugo Violeta
a Centro Interamericano de Recursos del Agua (CIRA) , Universidad Autónoma del Estado de México , Toluca , Estado de México , México.
b Centro Conjunto de Investigación en Química Sustentable , UAEM-UNAM, Carretera Toluca-Atlacomulco , Toluca , Estado de México , México.
Environ Technol. 2017 Feb;38(4):433-442. doi: 10.1080/09593330.2016.1196740. Epub 2016 Jun 29.
The aim of this work was to implement a coupled system, a monopolar Electrocoagulation (EC)-Electrooxidation (EO) processes, for the treatment of soft drink wastewater. For the EC test, Cu-Cu, anode-cathode were used at current densities of 17, 51 and 68 mA cm. Only 37.67% of chemical oxygen demand (COD) and 27% of total organic carbon (TOC) were removed at 20 min with an optimum pH of 8, this low efficiency can be associated with the high concentration of inorganic ions which inhibit the oxidation of organic matter due to their complexation with copper ions. Later EO treatment was performed with boron-doped diamond-Cu electrodes and a current density of 30 Am. The coupled EC-EO system was efficient to reduce organic pollutants from initial values of 1875 mg L TOC and 4300 mg L COD, the removal efficiencies were 75% and 85%, respectively. Electric energy consumption to degrade a kilogram of a pollutant in the soft drink wastewater using EC was 3.19 kWh kg TOC and 6.66 kWh kg COD. It was concluded that the coupled system EC-EO was effective for the soft drink wastewater treatment, reducing operating costs and residence time, and allowing its reuse in indirect contact with humans, thus contributing to the sustainable reuse as an effluent of industrial wastewater.
这项工作的目的是实现一个耦合系统,即单极电凝(EC)-电氧化(EO)工艺,用于处理软饮料废水。在EC试验中,使用铜-铜电极作为阳极-阴极,电流密度分别为17、51和68 mA/cm²。在最佳pH值为8的条件下,20分钟时仅去除了37.67%的化学需氧量(COD)和27%的总有机碳(TOC),这种低效率可能与高浓度的无机离子有关,这些无机离子由于与铜离子络合而抑制了有机物的氧化。随后,使用硼掺杂金刚石-铜电极和30 A/m²的电流密度进行了EO处理。耦合的EC-EO系统能够有效地降低软饮料废水中的有机污染物,初始TOC值为1875 mg/L,COD值为4300 mg/L,去除效率分别为75%和85%。使用EC降解软饮料废水中一千克污染物的电能消耗为3.19 kWh/kg TOC和6.66 kWh/kg COD。得出的结论是,耦合系统EC-EO对软饮料废水处理有效,降低了运营成本和停留时间,并允许其在与人类间接接触的情况下再利用,从而有助于将其作为工业废水排放物进行可持续再利用。