Department of Chemistry, Gurukula Kangri Vishwavidyalaya, Haridwar 249404, India.
Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa.
Bioresour Technol. 2016 Sep;216:1066-76. doi: 10.1016/j.biortech.2016.05.106. Epub 2016 May 28.
Cellulose is a biodegradable, renewable, non-meltable polymer which is insoluble in most solvents due to hydrogen bonding and crystallinity. Natural cellulose shows lower adsorption capacity as compared to modified cellulose and its capacity can be enhanced by modification usually by chemicals. This review focuses on the utilization of cellulose as an adsorbent in natural/modified form or as a precursor for activated carbon (AC) for adsorbing substances from water. The literature revealed that cellulose can be a promising precursor for production of activated carbon with appreciable surface area (∼1300m(2)g(-1)) and total pore volume (∼0.6cm(3)g(-1)) and the surface area and pore volume varies with the cellulose content. Finally, the purpose of review is to report a few controversies and unresolved questions concerning the preparation/properties of ACs from cellulose and to make aware to readers that there is still considerable scope for future development, characterization and utilization of ACs from cellulose.
纤维素是一种可生物降解的、可再生的、不可熔融的聚合物,由于氢键和结晶度的存在,它在大多数溶剂中都不溶解。与改性纤维素相比,天然纤维素的吸附能力较低,其吸附能力可以通过化学改性来增强。本综述重点介绍了纤维素作为吸附剂(天然/改性形式)或作为活性炭(AC)前体在水中吸附物质的用途。文献表明,纤维素可以作为生产具有可观比表面积(约 1300m2g-1)和总孔体积(约 0.6cm3g-1)的活性炭的有前途的前体,表面积和孔体积随纤维素含量而变化。最后,综述的目的是报告关于从纤维素制备/性质的活性炭的一些争议和未解决的问题,并使读者意识到从纤维素制备活性炭的未来发展、表征和利用仍有很大的空间。