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土工合成材料、应用及生态毒理学——综述。

Geotextile composition, application and ecotoxicology-A review.

机构信息

Institute for Environmental Studies (IVM), VU University Amsterdam, De Boelelaan 1087, 1081HV Amsterdam, The Netherlands.

Institute for Environmental Studies (IVM), VU University Amsterdam, De Boelelaan 1087, 1081HV Amsterdam, The Netherlands.

出版信息

J Hazard Mater. 2016 Nov 5;317:640-655. doi: 10.1016/j.jhazmat.2016.04.060. Epub 2016 Apr 30.

Abstract

Geosynthetics is the umbrella term for thin, flexible material sheets applied in civil and environmental engineering, of which geotextiles form the largest group. Most geotextiles consist of a polymer from the polyolefin, polyester or polyamide family, and additives to improve their stability. The polymer may degrade into microplastic particles over time and under various conditions and can cause adverse effects, as species may ingest these particles or encounter adverse effects due to the interference of the particles with e.g. their photosynthesis system in the case of algae. Leaching of additives may occur from the intact material, as they are often not covalently bound to the polymer backbone, but is greatly enhanced when micro-sized plastic particles have been formed. A total of 42 polymer additives were identified, of which 26 had ecotoxicity information available in terms of a REACH persistence, toxicity and bioaccumulation (PBT) assessment. Of these, 15 were classified as (very) persistent and 2 as toxic. A survey to assess potential toxicity of the remaining 16 substances revealed that no ecotoxicity studies had been performed on 13 of these compounds. For 3 compounds, other toxicity data was found, as well as of several chemical groups known to be used as additives in geotextiles. The current knowledge is thus lacking in two domains: on the one hand, ecotoxicity data is scarce as many substances have not yet been the subject of ecotoxicological studies. On the other hand, in situ toxic effects might be missed by the current approach of single compound toxicity testing. Moreover, environmental occurrence data of the additives are extremely scarce.

摘要

土工合成材料是应用于土木和环境工程中的薄而柔韧的材料薄片的统称,其中土工织物构成最大的群体。大多数土工织物由聚烯烃、聚酯或聚酰胺家族的聚合物和添加剂组成,以提高其稳定性。随着时间的推移和在各种条件下,聚合物可能会降解成微塑料颗粒,并可能产生不利影响,因为某些物种可能会摄入这些颗粒,或者由于颗粒与藻类的光合作用系统相互干扰等原因而受到不利影响。添加剂可能会从完整的材料中浸出,因为它们通常与聚合物主链没有共价键合,但当形成微尺寸的塑料颗粒时,浸出会大大增强。总共鉴定出 42 种聚合物添加剂,其中 26 种在 REACH 持久性、毒性和生物累积性 (PBT) 评估方面具有生态毒性信息。其中,15 种被归类为(非常)持久性,2 种具有毒性。一项评估其余 16 种物质潜在毒性的调查显示,其中 13 种化合物尚未进行生态毒性研究。对于 3 种化合物,发现了其他毒性数据,以及一些已知用于土工织物添加剂的化学基团的毒性数据。因此,目前的知识在两个领域都存在不足:一方面,由于许多物质尚未进行生态毒理学研究,因此生态毒性数据稀缺。另一方面,当前的单一化合物毒性测试方法可能会错过原位毒性效应。此外,添加剂的环境出现数据极其稀缺。

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