盐酸化学吸附诱导层状钴膦酰基三唑配位聚合物发生剧烈的磁结构转变。
HCl chemisorption-induced drastic magneto-structural transformation in a layered cobalt-phosphonotriazolate coordination polymer.
作者信息
Zhang Weiquan, Wang Dianpeng, Zhu Lin, Zhai Fupeng, Weng Linhong, Sun Jinyu, Ling Yun, Chen Zhenxia, Zhou Yaming
机构信息
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai, 200433, China.
出版信息
Dalton Trans. 2016 Jul 14;45(26):10510-3. doi: 10.1039/c6dt01363e. Epub 2016 Jun 13.
PMID:27294584
Abstract
The chemisorption of gaseous HCl molecules in a two-dimensional coordination polymer results in subtle changes in its structure and instigates a drastic modification from antiferro- to ferromagnetic properties.
摘要
气态HCl分子在二维配位聚合物中的化学吸附导致其结构发生细微变化，并引发从反铁磁到铁磁性质的剧烈转变。
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