具有对称多齿二酰腙配体的单链 {Gd18} 纳米轮。
A single-stranded {Gd18} nanowheel with a symmetric polydentate diacylhydrazone ligand.
机构信息
Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China.
出版信息
Chem Commun (Camb). 2016 Jul 7;52(53):8297-300. doi: 10.1039/c6cc02208a. Epub 2016 Jun 14.
PMID:27296972
Abstract
An unprecedented {Gd18} nanowheel was solvothermally synthesized with a novel diacylhydrazone ligand. It features a rare single-stranded skeleton just like a Reuleaux triangle with vertices buckled in, represents the highest nuclearity and largest size in lanthanide (Ln) wheels reported so far, and shows a large magnetocaloric effect (MCE).
摘要
一种前所未有的{Gd18}纳米轮采用新型二酰腙配体溶剂热合成。它具有罕见的单链骨架，就像一个带有内凹顶角的雷莱三角形，代表了目前报道的镧系（Ln）轮中最高的核性和最大的尺寸，并表现出较大的磁热效应（MCE）。
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