Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China.
Chem Commun (Camb). 2016 Jul 7;52(53):8297-300. doi: 10.1039/c6cc02208a. Epub 2016 Jun 14.
An unprecedented {Gd18} nanowheel was solvothermally synthesized with a novel diacylhydrazone ligand. It features a rare single-stranded skeleton just like a Reuleaux triangle with vertices buckled in, represents the highest nuclearity and largest size in lanthanide (Ln) wheels reported so far, and shows a large magnetocaloric effect (MCE).
一种前所未有的{Gd18}纳米轮采用新型二酰腙配体溶剂热合成。它具有罕见的单链骨架，就像一个带有内凹顶角的雷莱三角形，代表了目前报道的镧系（Ln）轮中最高的核性和最大的尺寸，并表现出较大的磁热效应（MCE）。
