具有直接连接烷基链的阴离子响应性π电子体系的无离子和离子对组装体。
Ion-Free and Ion-Pairing Assemblies of Anion-Responsive π-Electronic Systems Possessing Directly Linked Alkyl Chains.
作者信息
Haketa Yohei, Katayama Daisuke, Fukunaga Shinya, Bando Yuya, Sakurai Tsuneaki, Matsuda Wakana, Seki Shu, Maeda Hiromitsu
机构信息
Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu, 525-8577, Japan.
Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto, 615-8510, Japan.
出版信息
Chem Asian J. 2016 Jul 20;11(14):2025-9. doi: 10.1002/asia.201600712. Epub 2016 Jun 30.
Alkyl-substituted pyrrole-based anion-responsive π-electronic systems formed supramolecular gels and liquid crystals through effective π-π stacking and van der Waals interactions. The addition of chloride as a planar cation salt afforded ion-pairing assemblies as soft materials comprising planar receptor-Cl(-) complexes and the cation.
基于烷基取代吡咯的阴离子响应性π电子体系通过有效的π-π堆积和范德华相互作用形成超分子凝胶和液晶。添加氯化物作为平面阳离子盐可提供离子对组装体，作为包含平面受体-Cl(-)络合物和阳离子的软材料。
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