Lakshmi Vellanki, Haketa Yohei, Yamakado Ryohei, Yasuda Nobuhiro, Maeda Hiromitsu
Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu 525-8577, Japan.
Research and Utilization Division, Japan Synchrotron Radiation Research Institute, Sayo 679-5198, Japan.
Chem Commun (Camb). 2017 Mar 30;53(27):3834-3837. doi: 10.1039/c7cc01551h.
Pyrrole-4-aryl-substituted dipyrrolyldiketone BF complexes as anion-responsive π-electronic molecules were synthesized via a 3,5-dimethylpyrrole precursor. Mesophases were observed in derivatives that possessed long alkyl chains on the pyrrole-4-aryl groups along with their anion complexes as ion-pairing assemblies in combination with appropriate cations.
通过3,5-二甲基吡咯前体合成了吡咯-4-芳基取代的二吡咯二酮BF配合物作为阴离子响应性π电子分子。在吡咯-4-芳基上具有长烷基链的衍生物及其阴离子配合物中观察到中间相，这些配合物作为离子对组装体与适当的阳离子结合。
