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改良电场作用下铜尾矿在电动力学修复过程中的电学行为

Electrical Behavior of Copper Mine Tailings During EKR with Modified Electric Fields.

作者信息

Rojo Adrian, Hansen Henrik K, Monárdez Omara, Jorquera Carlos, Santis Paulina, Inostroza Paula

机构信息

Universidad Técnica Federico Santa María, Casilla 110-V, Valparaiso, Chile.

出版信息

Bull Environ Contam Toxicol. 2017 Mar;98(3):304-309. doi: 10.1007/s00128-016-1858-8. Epub 2016 Jun 21.

DOI:10.1007/s00128-016-1858-8
PMID:27329109
Abstract

Electro-kinetic remediation (EKR) with sinusoidal electric field obtained simultaneously with DC/AC voltage reduce the polarization of the EKR with DC voltage. The DC voltage value defines the presence of a periodic polarity reversal of the cell and the electrical charge for electro-kinetic transport. In this case, the AC frequency favors the breaking of polarization conditions resulting from the EKR with DC voltage. However, with high frequencies a negative effect occurs where the tailings behave as a filter circuit, discriminating frequencies of an electric signal. The goal of this work is to analyse the electrical behaviour of tailings in EKR experiments. The conditions selected were: DC/AC voltages: 10/15 and 20/25 V (peak values), and AC voltage frequencies 50-2000 Hz. When the AC frequency reaches 2000 Hz, the copper removal tends to zero, indicating that the tailing behaves as a high-pass filter in which the DC voltage was filtered out.

摘要

通过直流/交流电压同时获得的正弦电场进行电动修复(EKR),可减少直流电压下EKR的极化现象。直流电压值决定了电池周期性极性反转的存在以及电动传输的电荷。在这种情况下,交流频率有利于打破直流电压下EKR产生的极化条件。然而,在高频时会出现负面影响,尾矿表现为滤波电路,区分电信号的频率。这项工作的目的是分析EKR实验中尾矿的电学行为。选择的条件为:直流/交流电压:10/15和20/25 V(峰值),以及交流电压频率50 - 2000 Hz。当交流频率达到2000 Hz时,铜去除率趋于零,表明尾矿表现为高通滤波器,其中直流电压被滤除。

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