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使用硫酸活化材料从水溶液中去除碱性紫14

Removal of Basic Violet 14 from aqueous solution using sulphuric acid activated materials.

作者信息

Suresh S

机构信息

Department of Chemistry, St. Joseph University in Tanzania, Arusha Campus, Arusha, Tanzania.

出版信息

Springerplus. 2016 May 17;5:633. doi: 10.1186/s40064-016-2294-2. eCollection 2016.

Abstract

In this study the adsorption of Basic Violet, 14 from aqueous solution onto sulphuric acid activated materials prepared from Calophyllum inophyllum (CS) and Theobroma cacao (TS) shells were investigated. The experimental data were analysed by Langmuir, Freundlich and Temkin isotherm models. The results showed that CS has a superior adsorption capacity compared to the TS. The adsorption capacity was found to be 1416.43 mg/g for CS and 980.39 mg/g for TS. The kinetic data results at different concentrations were analysed using pseudo first-order and pseudo-second order model. Boyd plot indicates that the dye adsorption onto CS and TS is controlled by film diffusion. The adsorbents were characterised by scanning electron microscopy. The materials used in this study were economical waste products and hence can be an attractive alternative to costlier adsorbents for dye removal in industrial wastewater treatment processes.

摘要

在本研究中,考察了碱性紫14从水溶液中吸附到由红厚壳(CS)和可可(TS)壳制备的硫酸活化材料上的情况。实验数据采用朗缪尔、弗伦德里希和坦金等温线模型进行分析。结果表明,与TS相比,CS具有更高的吸附容量。发现CS的吸附容量为1416.43 mg/g,TS的吸附容量为980.39 mg/g。使用伪一级和伪二级模型分析了不同浓度下的动力学数据结果。博伊德图表明,染料在CS和TS上的吸附受膜扩散控制。通过扫描电子显微镜对吸附剂进行了表征。本研究中使用的材料是经济的废品,因此对于工业废水处理过程中去除染料而言,它们可能是比成本更高的吸附剂更具吸引力的替代品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/02c7/4870511/55c5206bc8d5/40064_2016_2294_Fig1_HTML.jpg

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