海胆状金纳米颗粒在有机薄膜太阳能电池中的作用。
Effect of urchin-like gold nanoparticles in organic thin-film solar cells.
作者信息
Pangdam Apichat, Nootchanat Supeera, Ishikawa Ryousuke, Shinbo Kazunari, Kato Keizo, Kaneko Futao, Thammacharoen Chuchaat, Ekgasit Sanong, Baba Akira
机构信息
Graduate School of Science and Technology, Niigata University, 8050, Ikarashi 2-nocho, Nishi-ku, Niigata 950-2181, Japan.
出版信息
Phys Chem Chem Phys. 2016 Jul 21;18(27):18500-6. doi: 10.1039/c6cp02373h. Epub 2016 Jun 24.
UNLABELLED
In this study, urchin-like gold nanoparticles (UL-AuNPs) are used in the fabrication of organic thin-film solar cells (OSCs). UL-AuNPs, which have gold nanothorns on their surface, enhance light accumulation by acting as light-trapping materials. This is due to the enhanced electric field and light scattering attributed to the nanothorns on the surface of the nanoparticles. UL-AuNPs were incorporated into a poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (
PEDOT
PSS) thin-film layer of organic thin-film solar cells (OSCs). UV-vis spectra, atomic force microscopy (AFM) images, current density versus voltage properties, and the impedance spectra of the fabricated devices were recorded at various concentrations of UL-AuNPs. We found that the efficiency of the OSCs with UL-AuNPs was not only higher than that of a reference cell without nanoparticles but also higher than that of OSCs with spherical AuNPs. Finite-difference time-domain (FDTD) simulation indicated that the electric field around the UL-AuNPs increased due to the presence of nanothorns.
未标注
在本研究中，海胆状金纳米颗粒（UL-AuNPs）被用于制造有机薄膜太阳能电池（OSCs）。表面带有金纳米刺的UL-AuNPs作为光捕获材料增强了光的积累。这是由于纳米颗粒表面的纳米刺增强了电场和光散射。UL-AuNPs被掺入有机薄膜太阳能电池（OSCs）的聚（3,4-乙撑二氧噻吩）：聚（苯乙烯磺酸盐）（PEDOT：PSS）薄膜层中。在不同浓度的UL-AuNPs下记录了所制备器件的紫外可见光谱、原子力显微镜（AFM）图像、电流密度与电压特性以及阻抗谱。我们发现，含有UL-AuNPs的OSCs的效率不仅高于不含纳米颗粒的参考电池，而且高于含有球形AuNPs的OSCs。时域有限差分（FDTD）模拟表明，由于纳米刺的存在，UL-AuNPs周围的电场增强。
Zotero 插件