安德森型烷氧基多钒酸盐簇作为前所未有的二级结构单元用于构建金属有机多面体。
Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal-organic polyhedra.
作者信息
Zhang Yu-Teng, Wang Xin-Long, Li Shuang-Bao, Gong Ya-Ru, Song Bai-Qiao, Shao Kui-Zhan, Su Zhong-Min
机构信息
Institute of Functional Material Chemistry, Local United Engineering Lab for Power Battery, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China.
出版信息
Chem Commun (Camb). 2016 Aug 11;52(62):9632-5. doi: 10.1039/c6cc04583a. Epub 2016 Jul 1.
Unprecedented Anderson-like alkoxo-polyoxovanadate V6O6(OCH3)9(μ6-SO4)(COO)3 polyanions can serve as 3-connected second building units (SBUs) that assemble with dicarboxylate or tricarboxylate ligands to form a new family of metal organic tetrahedrons of V4E6 and V4F4 type (V = vertex, E = edge, and F = face). To our knowledge, this alkoxo-polyoxovanadate-based SBU is the first ever reported.
前所未有的类安德森型烷氧基多钒酸盐V6O6(OCH3)9(μ6 - SO4)(COO)3聚阴离子可作为三连接二级结构单元（SBUs），与二羧酸或三羧酸配体组装形成新的V4E6和V4F4型金属有机四面体家族（V = 顶点，E = 边，F = 面）。据我们所知，这种基于烷氧基多钒酸盐的SBUs是首次报道。
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