University of Florida, Department of Chemistry, Center for Catalysis, Gainesville, FL 32611-7200, USA.
Chem Commun (Camb). 2016 Jul 28;52(59):9295-8. doi: 10.1039/c6cc04671a. Epub 2016 Jul 1.
A μ3-sulfide bridged triiron cluster(ii,ii,iii) supported by a cyclophane ligand undergoes metal-based reduction to yield an all-ferrous species. The latter complex incorporates a three-coordinate iron center that provides an accessible coordination site to a solvent molecule.
一个由环芳配体支撑的μ3-硫化物桥联三铁簇(ii,ii,iii)经历基于金属的还原反应,生成全铁物种。后者配合物包含一个三配位的铁中心,为一个溶剂分子提供了一个可及的配位位点。