Kastratović Vlatko, Jaćimović Željko, Bigović Miljan, Đurović Dijana, Krivokapić Slađana
Faculty of Natural Sciences and Mathematics, University of Montenegro, G. Washington Street P., 81000, Podgorica, Montenegro.
Faculty of Technology and Metallurgy, University of Montenegro, G. Washington Street P., 81000, Podgorica, Montenegro.
Environ Monit Assess. 2016 Aug;188(8):449. doi: 10.1007/s10661-016-5459-0. Epub 2016 Jul 6.
The environmental mobility and geochemical partitioning of ten metals were examined in sediments collected from the six locations around Lake Skadar in Montenegro. A three-step sequential extraction procedure was used to determine the distribution of the metals in various substrates of lacustrine sediments, and the concentrations were measured in the liquid extract by ICP-OES. The largest portion of the total amount of cadmium, strontium and manganese can be found in sediment bound to the hydrated iron and manganese oxides; cobalt, lead, copper and nickel in the oxidizable fraction and the highest portion of chromium, vanadium and zinc are in the residual fraction. The most mobilized and potentially mobile metals are strontium, cadmium and cobalt while the most immobilized metals are chromium, vanadium and zinc. Based on geochemical parameters, an assessment of sediment contamination by the investigated metals was performed and the results showed potential risks ranging from "no risk" to "low risk" to the environment.
对从黑山斯卡达尔湖周边六个地点采集的沉积物中十种金属的环境迁移性和地球化学分配进行了研究。采用三步连续提取程序来确定金属在湖相沉积物各种基质中的分布,并通过电感耦合等离子体发射光谱仪(ICP - OES)测定液体提取物中的浓度。镉、锶和锰总量的最大部分存在于与水合铁和锰氧化物结合的沉积物中;钴、铅、铜和镍存在于可氧化部分,而铬、钒和锌的最高部分存在于残余部分。迁移性最强和潜在迁移性最强的金属是锶、镉和钴,而固定性最强的金属是铬、钒和锌。基于地球化学参数,对所研究金属造成的沉积物污染进行了评估,结果表明对环境的潜在风险范围从“无风险”到“低风险”。