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二元混合溶剂中的反向溶剂化显色:以4-(硝基苯乙烯基)酚盐为探针的案例研究

Reverse solvatochromism in solvent binary mixtures: a case study using a 4-(nitrostyryl)phenolate as a probe.

作者信息

Stock Rafaela I, Schramm Adriana D S, Rezende Marcos C, Machado Vanderlei G

机构信息

Departamento de Química, Universidade Federal de Santa Catarina, UFSC, CP 476, Florianópolis, SC 88040-900, Brazil.

Facultad de Química y Biología, Universidad de Santiago, Av. B. O'Higgins 3363, Santiago, Chile.

出版信息

Phys Chem Chem Phys. 2016 Jul 27;18(30):20266-9. doi: 10.1039/c6cp03875a.

DOI:10.1039/c6cp03875a
PMID:27405705
Abstract

A 4-(nitrostyryl)phenolate was synthesized and its use in pure solvents revealed a reversion in solvatochromism. Solutions of a dye in binary solvent mixtures, using as components the solvents in the region of the occurrence of the reversion, provided the first case in the literature of reverse solvatochromism in a binary mixture.

摘要

合成了一种4-(硝基苯乙烯基)酚盐,其在纯溶剂中的应用显示出溶剂化显色的反转。以发生反转区域的溶剂为组分,将染料溶解在二元溶剂混合物中,这在文献中首次报道了二元混合物中的反向溶剂化显色现象。

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