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基于钴酸锰酸镍三元 1D 杂化纳米管的高性能超级电容器电极。

High-Performance Supercapacitor Electrode Based on Cobalt Oxide-Manganese Dioxide-Nickel Oxide Ternary 1D Hybrid Nanotubes.

机构信息

Large Area Device Laboratory, Centre for Nano and Soft Matter Sciences , Jalahalli, Bengaluru 560013, India.

Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences , Block JD, Sector III, Salt Lake City, Kolkata 700106, India.

出版信息

ACS Appl Mater Interfaces. 2016 Aug 17;8(32):20786-92. doi: 10.1021/acsami.6b05933. Epub 2016 Aug 1.

Abstract

We report a facile method to design Co3O4-MnO2-NiO ternary hybrid 1D nanotube arrays for their application as active material for high-performance supercapacitor electrodes. This as-prepared novel supercapacitor electrode can store charge as high as ∼2020 C/g (equivalent specific capacitance ∼2525 F/g) for a potential window of 0.8 V and has long cycle stability (nearly 80% specific capacitance retains after successive 5700 charge/discharge cycles), significantly high Coulombic efficiency, and fast response time (∼0.17s). The remarkable electrochemical performance of this unique electrode material is the outcome of its enormous reaction platform provided by its special nanostructure morphology and conglomeration of the electrochemical properties of three highly redox active materials in a single unit.

摘要

我们报告了一种简便的方法来设计 Co3O4-MnO2-NiO 三元混合 1D 纳米管阵列,将其用作高性能超级电容器电极的活性材料。这种新的超级电容器电极在 0.8 V 的电势窗口下可以存储高达 ∼2020 C/g(等效比电容 ∼2525 F/g)的电荷,具有长循环稳定性(经过连续 5700 次充放电循环后,比电容保留率接近 80%),高库仑效率和快速响应时间(约 0.17s)。这种独特电极材料的显著电化学性能是其特殊纳米结构形态和三种高氧化还原活性材料在单个单元中聚集所提供的巨大反应平台的结果。

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